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Resistance of Silicon-Containing Carbonized Lignin to Atomic Oxygen Erosion

机译:含硅碳化木质素对原子氧侵蚀的抗性

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Spacecraft in low Earth orbit (LEO) are exposed to atomic oxygen (AO). It is thus important to develop an environmentally friendly material that can be applied to the outer surfaces of spacecraft in LEO to protect them against AO. Carbonized material containing electroconductive graphitic microlayers is promising for this purpose. We produced carbonized lignin (CW) by separating wood in L-lactic acid and we investigated the AO erosion resistances of CW and CW containing Si. X-ray photoelectron spectroscopy (XPS) revealed that the O/C ratio increased on AO exposure. The CW sample without Si and CW samples containing 20% and 40% Si exhibited less erosion than CW samples containing 5% and 10% Si. XPS revealed that the presence of Si resulted in the formation of SiO_2 on the sample surface. For CW with Si contents of 20% and 40%, the SiO_2 coverage may be sufficiently large to prevent attack by AO.
机译:低地球轨道(LEO)的航天器暴露于原子氧(AO)。因此,可以开发一种环保材料,这些材料可以应用于狮子座的太空船的外表面以保护它们免受AO。含有导电石墨微层的碳化材料是有望的。我们通过在L-乳酸中分离木材生产碳化的木质素(CW),我们研究了CW和CW含有Si的AO腐蚀抗性。 X射线光电子能谱(XPS)揭示了O / C比率在AO暴露上增加。没有Si和CW样品的CW样品含有20%和40%Si的CW样品比含有5%和10%Si的CW样品较少。 XPS显示Si的存在导致样品表面上的SiO_2。对于Si含量为20%和40%的CW,SiO_2覆盖率可能足够大以防止AO攻击。

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