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MECHANICAL CHARACTERIZATION OF HONEYCOMB ELECTRODE SUPPORT STRUCTURES

机译:蜂窝电极支撑结构的机械表征

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To reduce the internal ohmic loss of the conducting electrolyte in a solid oxide fuel cell, it is fabricated as thin as possible, forcing designers to rely on either the anode or cathode as the structural supporting member. In order to supply oxygen efficiently to the electrode/electrolyte interface, the electrodes typically contain 30 - 50 vol. % open porosity. This high level of porosity significantly reduces the mechanical performance of the structure. In this study, the structure of electrodes has been modified using an underlying zirconia honeycomb laminated to the zirconia electrolyte. The structure increases the strength of the electrode structure and should allow for thinner electrodes, increasing gas transport to the electrolyte and reduced overpotential. Strengths of 70% and 82.5% open channel material were determined to be 250 MPa and 240 MPa, respectively. Honeycomb theory fails to predict failure stresses for ceramic materials; however, Object Oriented Finite Element (OOF) modeling identifies failure occurring at cell boundaries.
机译:为了减少固体氧化物燃料电池中的导电电解质的内部欧姆损耗,它尽可能薄地制造,迫使设计人员依赖于阳极或阴极作为结构支撑构件。为了高效地向电极/电解质界面供应氧气,电极通常含有30-50体积。 %开放孔隙度。这种高水平的孔隙度显着降低了结构的机械性能。在该研究中,使用层压在氧化锆电解质上的下面的氧化锆蜂窝进行改性电极结构。该结构增加了电极结构的强度,并且应该允许较薄的电极,增加气体输送到电解质并减少过势。 70%和82.5%的开放通道材料的强度分别测定为250MPa和240MPa。蜂窝理论未能预测陶瓷材料的失效应力;然而,面向对象的有限元(OOF)建模识别在单元边界处发生的故障。

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