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Mesoscopic Patterning Induced by Co-deposition of C_(60) and Ni on the MgO(l00) Single Crystal

机译:通过在MgO(L00)单晶的C_(60)和Ni的共沉积诱导的介观图案

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We report on an unusual phenomenon of pattern formation in the mixture of Ni and C_(60) co-deposited on the single crystal of MgO(l00). Under certain deposition kinetics an array of periodic stripes was formed. The stripes consist of sub-half-micrometer Ni droplets (embedded in the complex Ni-C base) and encompassed with a polymerized C_(60) rind. The stripes are bound to the thin double-layer platform consisting of the epitaxial Ni and amorphous C (a-C) layers. During co-deposition the C_(60) molecules partly disintegrate and transform towards the a-C structures. Accumulation of a-C (immiscible with Ni) may induce thermodynamic instability in the system and trigger the process of spontaneous partitioning. As a principal mechanism of the stripe formation a sequential drift and co-ordinate release of the incited instability was proposed.
机译:我们报道了在MgO(L00)的单晶中的Ni和C_(60)的混合物中的图案形成的不寻常现象。在某些沉积动力学下,形成一系列周期条纹。条纹由亚半千分尺Ni液滴(嵌入复合Ni-C碱中),并包含聚合的C_(60)rind。条纹与由外延Ni和非晶C(A-C)层组成的薄双层平台。在共沉积期间,C_(60)分子部分崩解并朝向A-C结构转换。 A-C的累积(不混溶NI)可以在系统中引起热力学不稳定性,并触发自发隔置的过程。作为条纹形成的主要机制,提出了煽动不稳定的顺序漂移和坐标释放。

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