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Bubble Nucleation Rates By Pressure Pulse Experiments

机译:压力脉冲实验的泡沫成核速率

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We designed a precision method for observation of liquid-gas first order phase-transitions. At first we prepare a gas-saturated liquid of well known composition. Then we induce the phase transition by a rapid pressure quench under simultaneous detection of pressure and scattered light. To this end the proceeding phase separation is detected by time resolved light-scattering at constant angle (CAMS). Specifically, we obtain detailed information about the microscopic characteristics of the phase separation process (nucleation / spinodal decomposition), the maximal pressure undershoot, the expansion rate and the preselected growth of the newly evolving phase as well as the nucleation rate. It is the aim of the study to measure homogeneous nucleation rates as function of supersaturation in gas-saturated liquids at constant temperature and to compare the results with classical and other nucleation theories.
机译:我们设计了一种精密方法,用于观察液体 - 气体的第一阶相转移。首先,我们制备众所周知的众所周知组合物的气体饱和液体。然后我们通过同时检测压力和散射光的快速压力淬火诱导相位过渡。为此,通过以恒定角度(凸轮)分辨的光散射来检测前进的相分离。具体地,我们获得了关于相分离过程的微观特性(成核/旋顶分解)的微观特性的详细信息,最大压力下冲,膨胀率和新进化阶段的预选生长以及成核速率。该研究的目的是测量均匀成核率作为在恒定温度下在气饱和液体中过饱和度的函数,并将结果与​​古典和其他成核理论进行比较。

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