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APPLICATION OF ORGANIC POLYMER IN COKE MAKING-TATA STEEL SCENARIO

机译:有机聚合物在焦炭制作 - 塔塔钢方案中的应用

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The use of blends of coals of different origin and quality is the normal practice in the coke making industry. In addition, other types of carbonaceous materials (additives) are also included in the formulation of industrial blends [1-3] for coke production. Different types of additives can be introduced in the coke oven e.g. non-coking coals such as anthracite and bituminous materials like coal-tar or coal-tar pitch. Furthermore, materials from petroleum processing have also been used as additives in coke production. In recent years, due to environmental issues, the introduction of residues of different origins has been the subject of many research works [4-5].In Tata Steel, different carbonaceous materials has been tried and tested as a component of blend. The main criteria for blend design is desirable coke strength and safe battery operation. Keeping these two points in mind trial conducted with different additives. In Tata Steel, Anthracite was tried out in coal blend. Though there was the apprehension of coke quality deterioration, its low volatile content, higher specific gravity and Tata Steel's stamp charging facility, helped to use it successfully in cokemaking . Tata Steel has also tried waste plastics and coal tar pitch as additive[6-7].With this background, in this paper the effect of one organic polymer named phenolic resin has been studied. It is well known that condensation of a phenol and aldehyde provides materials, curable to thermoset phenolic resins. Base catalyzed condensation, employing at least about a stoichiometric of aldehyde provides condensates, known as resoles, whereas acid catalyst and deficiency of aldehyde, provides novalacs. Phenolic resin binder most popularly used for the formation of briquettes [8].
机译:使用不同起源和质量的煤炭混合是焦炭制作行业的正常实践。此外,其他类型的碳质材料(添加剂)也包括在工业共混物的制剂中,用于焦炭生产的工业共混物[1-3]。可以在焦炉中引入不同类型的添加剂。非焦化煤,如无烟煤和沥青材料,如煤焦油或煤焦油沥青。此外,来自石油加工的材料也被用作焦炭生产中的添加剂。近年来,由于环境问题,不同起源的残留物的引入一直是许多研究工作的主题[4-5]。塔塔钢,不同的碳质材料已经尝试并测试为混合物的组成部分。混合设计的主要标准是理想的焦度和安全电池运行。用不同的添加剂进行思维试验,保持这两点。在塔塔钢中,在煤混合物中尝试了无烟煤。虽然有令人置信的焦炭质量恶化,但其低位挥发性含量,更高的重力和塔塔钢邮票充电设施,有助于在炼室中成功使用。塔塔钢也尝试了废塑料和煤焦油沥青作为添加剂[6-7]。在此背景下,研究了一种名为酚醛树脂的一种有机聚合物的效果。众所周知,苯酚和醛的缩合提供材料,可固化热固性酚醛树脂。基础催化的缩合,至少用于醛化学计量的化学计量提供缩合物,称为分子,而酸催化剂和醛的缺乏提供Novalacs。酚醛树脂粘合剂最普遍用于聚集的形成[8]。

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