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Polarized waveguide Raman spectroscopy of the thorium phosphate xerogel thin films

机译:偏极化波导拉曼磷酸盐Xerogel薄膜的光谱光谱

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Due to the difficulties in geometrical arrangement, up to now the polarization arrangement for waveguide Raman spectroscopy (WRS) was limited to only a few simple configurations. In this report, we present the experiments in extending polarization configurations for WRS. The resulted polarized WRS spectra of thorium phosphate xerogel thin films will be presented. In the region of Raman shift from 850 to 1200 cm$+$MIN@1$/, two components with different polarization behavior exist. Based on the symmetry arguments, these components are then identified to the different vibration modes of PO$-4$/$+3$MIN$/ ions. From the spectra it is also concluded that the film is amorphous and isotropic and has chain-like structure.
机译:由于几何排列的困难,到目前为止,WAVALIDE拉曼光谱(WRS)的偏振装置仅限于仅几个简单的配置。在本报告中,我们在延长WRS延伸极化配置中的实验。将介绍所得到的焦磷酸氧化钇薄膜的偏振Wrs光谱。在拉曼地区从850到1200 cm $ + $ min @ 1 $ /,存在具有不同偏振行为的两个组件。基于对称性参数,这些组件被识别到PO $ -4 $ / $ + 3 $ /离子的不同振动模式。来自光谱,也得出结论,薄膜是无定形和各向同性的并且具有链状结构。

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