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A Theoretical and Practical Evaluation of Struvite Control and Recovery: Two Case Studies

机译:鸟粪石控制和恢复的理论和实践评估:两个案例研究

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The Miami-Dade Water and Sewer Department’s (MDWASD) operating staff has identifiedstruvite deposits in the solids handling process equipment at the Central District WastewaterTreatment Plant (CDWWTP) and the South District Wastewater Treatment Plant (SDWWTP).Struvite, also known as magnesium ammonia phosphate (Mg NH_4-PO_4·6H_2O) is a hard compoundsimilar in appearance to fiberglass which precipitates out of solution, forms crystals andadheres to the piping system components. The anaerobic digestion of WAS releases into solutionammonia, phosphate and sometimes magnesium (otherwise present in the background) ions,which precipitate as struvite.Struvite formation is a common problem in wastewater treatment plants and can cause significantdamage to equipment, pumps, and piping. It is important to address any struvite problems asa significant struvite accumulation can lead to mechanical and process failures. Struvite depositshave been identified in the digester units, the digester piping system including valves and heatexchangers and the centrifuge dewatering units downstream of the digester system at both plants.The CDWWTP has had more severe struvite problems than the SDWWTP. During the periodfrom December 2009 through March 2010, the CDWWTP had at times relatively high concentrationsof effluent total suspended solids (TSS) which were linked to struvite precipitation in theplant.Currently, MDWASD is feeding Ferric Sulfate (Fe_2(SO_4)_3 (they have also tried Ferric Chloride(FeCl_3) to the influent of the centrifuges at the CDWWTP as a short term fix for resolving struviteprecipitation issues as well as improving the solids capture rate. Ferric is used to bind up thesoluble orthophosphate preventing it from forming struvite. This solution, however, has beencostly with an estimated ferric sulfate cost of $47,000 per month. The CDWWTP is also feedinggas scrubber water and chlorinated flushing water to the centrate in order to reduce the pH andreduce struvite precipitation.The SDWWTP has not added Ferric to the plant to reduce struvite precipitation, but has had todo extensive preventative maintenance (jetting out pipe lines) on a weekly basis to control struviteaccumulation.As a result, several short and long term solutions to struvite precipitation were evaluated includingthe OSTARA nutrient recovery process (as OSTARA Pearl? fertilizer), through pilot testing.In addition, bench scale tests were conducted to determine the most cost effective Ferric Sulfate
机译:迈阿密戴德市下水道局(MDWASD)的运营人员已确定 中心区废水中固体处理设备中的鸟粪石沉积物 处理厂(CDWWTP)和南区废水处理厂(SDWWTP)。 鸟粪石,也称为磷酸镁氨水(Mg NH_4-PO_4·6H_2O)是一种硬质化合物 外观类似于玻璃纤维,从溶液中沉淀出来,形成晶体, 遵守管道系统组件。 WAS的厌氧消化释放到溶液中 氨,磷酸根离子,有时还有镁离子(否则存在于背景中), 沉淀为鸟粪石。 鸟粪石的形成是废水处理厂中的常见问题,可能会导致显着的 损坏设备,泵和管道。解决任何鸟粪石问题很重要,因为 大量的鸟粪石堆积会导致机械和工艺故障。鸟粪石沉积 已在蒸煮器单元中确定,蒸煮器管道系统包括阀门和热量 两家工厂中消化系统下游的交换器和离心脱水单元。 与SDWWTP相比,CDWWTP的鸟粪石问题更为严重。在此期间 从2009年12月到2010年3月,CDWWTP的浓度有时较高 废水中总悬浮固体(TSS)的含量与鸟粪石沉淀有关 植物。 目前,MDWASD正在喂养硫酸铁(Fe_2(SO_4)_3(他们也尝试过氯化铁 (FeCl_3)作为CDWWTP离心机进水的短期解决方案,用于解决鸟粪石 沉淀问题以及提高固体捕获率。铁用于束缚 可溶性正磷酸盐,防止其形成鸟粪石。但是,这种解决方案一直是 费用昂贵,估计每月硫酸铁成本为47,000美元。 CDWWTP也正在喂养 气体洗涤器水和氯化冲洗水至浓缩液,以降低pH值和 减少鸟粪石沉淀。 SDWWTP尚未向工厂添加铁酸铁以减少鸟粪石沉淀,但必须 每周进行广泛的预防性维护(喷出管道)以控制鸟粪石 积累。 结果,对鸟粪石沉淀的几种短期和长期解决方案进行了评估,包括 通过中试测试确定OSTARA养分的恢复过程(如OSTARA Pearl?肥料)。 此外,还进行了台式规模测试,以确定最具成本效益的硫酸铁。

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