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AN INVESTIGATION OF THE PHOTOLUMINESCENCE AND TRANSMITTANCE OF CdS_(1-x)Te_x THIN FILMS

机译:CdS_(1-x)Te_x薄膜的光致发光和透射率的研究

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CdS_(1-x)Te_x thin films were prepared by first producing CdS:In thin films by the spray pyrolysis (SP) technique and then annealing the films in the presence of Te vapor in nitrogen atmosphere. X-Ray diffraction (XRD) measurements showed that the films are polycrystalline with the wurtzite structure. Transmittance measurements were recorded at room temperature in the wavelength range 400-900 run and used to deduce the absorbance. The first derivative of the absorbance was calculated and used to find the values of the bandgap energy, where more than one bandgap was obtained for each film. These results show that the films are inhomogeneous or the composition differs with location. The photoluminescence (PL) was recorded at T = 60 K and a deconvolution peak fit was performed for each spectrum. The results of the PL spectra are consistent with those obtained from the first derivative and confirm the inhomogeneity of the films.
机译:CdS_(1-x)Te_x薄膜的制备方法是,首先通过喷雾热解(SP)技术制备CdS:In薄膜,然后在氮气气氛中在Te蒸气存在的情况下对薄膜进行退火。 X射线衍射(XRD)测量表明该膜是具有纤锌矿结构的多晶。在室温下在400-900nm的波长范围内记录透射率测量值,并用于推导吸收率。计算吸光度的一阶导数,并用于找到带隙能量的值,其中每个薄膜获得一个以上的带隙。这些结果表明膜是不均匀的或组成随位置而不同。在T = 60 K处记录光致发光(PL),并对每个光谱进行去卷积峰拟合。 PL光谱的结果与从一阶导数获得的结果一致,并证实了膜的不均匀性。

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