首页> 外文会议>Proceedings of the 2010 5th IEEE International Conference on Nano/Micro Engineered and Molecular Systems >Morphology observation Of siloxane dendrimer(G1P-6Cl) LB film containing dendric core
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Morphology observation Of siloxane dendrimer(G1P-6Cl) LB film containing dendric core

机译:含树枝状核的硅氧烷树枝状大分子(G1P-6Cl)LB薄膜的形貌观察

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In this study, we use hybrid between dendritic core and phenyl group containing Hydrolysis of Tris(2-dichloromethylsilyl-2-phenyl-1-ethenyl)methylsilane(G1P-6Cl). It will prove nanosized, well defined, and highly branched macromolecules. Siloxan part have insulating property. But phenyl group have conductivity. We use the Langmuir-Blodgett (LB) method to deposit G1P-6Cl. Because LB technique provides many possibilities for the control of film thickness, dimensions, and molecular structures on nanometer scale. We examined the monolayer behavior by n-A isotherm at the air-water interface. The n-A curves indicated surface pressure of this LB film from liquid to solid state between 6 and 8 mN/m. The monolayer was deposited onto highly oriented pyrolytic graphite (HOPG) substrates by Y-type deposition at surface pressure 7.5 mN/m. We measured morphology of siloxane dendrimer(G1P-6Cl) LB films using SPM.
机译:在这项研究中,我们使用树突状核心和含有苯基的三(2-二氯甲基甲硅烷基-2-苯基-1-乙烯基)甲基硅烷(G1P-6Cl)水解水解混合物。它将证明是纳米级,定义明确且高度分支的大分子。硅氧烷部分具有绝缘性能。但是苯基具有导电性。我们使用Langmuir-Blodgett(LB)方法沉积G1P-6Cl。因为LB技术为控制纳米级的膜厚度,尺寸和分子结构提供了许多可能性。我们通过n-A等温线在空气-水界面处检查了单层行为。 n-A曲线表示该LB膜从液态到固态的表面压力在6到8 mN / m之间。通过Y型沉积以7.5 mN / m的表面压力将单分子层沉积到高度取向的热解石墨(HOPG)衬底上。我们使用SPM测量了硅氧烷树状大分子(G1P-6Cl)LB膜的形貌。

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