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Initial Processes of Proton Transfer in Salicylideneaniline Studied by Time-Resolved Photoelectron Spectroscopy

机译:通过时间分辨的光电子谱研究的水杨酰胺中质子转移的初始过程

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Excited state intramolecular proton transfer (ESIPT) in salicylideneaniline (SA) and selected derivatives substituted in para-position of the anilino group has been investigated by femtosecond time-resolved photoelectron spectroscopy (TRPES) and time-dependent density functional theory (TDDFT). The planarity of the molecule was found to be a key parameter to describe ESIPT.
机译:通过飞秒时间分辨的光电子能谱(TRPE)和时间依赖性密度泛函理论(TDDFT)研究了在苯基胺(SA)中取代的SalicylinyanInInIn(SA)和所选衍生物中的激发状态分子内质子转移(Esipt)和所选衍生物。发现分子的平面性是描述eSipt的关键参数。

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