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Carbon Nanotubes for Assessing the Structural Integrity of Composite Bonded Joints with Film Adhesives

机译:碳纳米管,用于评估具有薄膜胶粘剂的复合粘结接头的结构完整性

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This work analyses the capability of the application of self-sensing film adhesives for assessing the structural integrity of typical aeronautical bonded joints without altering its mechanical behavior. Tests have been carried out on carbon fiber reinforced polymer composites (CFRP) although the method has been also validated on aluminum substrates, showing that different types of strain and damage are detected depending on the characteristics of the joined materials. In both cases, the structural health monitoring of the bonded joints has been achieved. The developed technologies are based on the addition of carbon nanotubes (CNT) to the film adhesives in order to provide electrical conductivity to the different interfaces. The high conductivity and relative large aspect ratio of CNT result in percolation thresholds around 0.1% weight of carbon nanotubes in the adhesive. The CNT network formed in the adhesive offers significant potential to develop sensing for damage detection and health monitoring using direct-current measurements. Loads applied over the nanodoped adhesives produce damage (i.e. cracks, delaminations,...) appearance and/or damage progression in the material, that modifies the integrity of carbon networks and increases the electrical resistivity of the adhesive. Two different methods have been developed to deposit CNTs on film adhesives: innovative inkjet printing methods and mask methods. In both cases the CNTs used were stabilized in water solution to use a solvent that did not damage the behavior of the adhesive. Then, the CNT solution was incorporated in the nanoreinforcement with controlled geometries over the films, providing local and controlled sensitivity to the bonded joints and giving information of the location of the damages, their characteristics and their propagations in an accurate way.
机译:这项工作分析了自感薄膜胶粘剂在不改变其机械性能的情况下评估典型航空粘合接头的结构完整性的能力。尽管该方法也已在铝基材上得到验证,但已对碳纤维增强聚合物复合材料(CFRP)进行了测试,结果表明,根据连接材料的特性,可以检测到不同类型的应变和损伤。在这两种情况下,都已实现了对粘合接头的结构健康监测。所开发的技术基于在薄膜胶粘剂中添加碳纳米管(CNT),以便为不同的界面提供导电性。 CNT的高电导率和相对较大的纵横比导致渗漏阈值占粘合剂中碳纳米管重量的0.1%左右。胶粘剂中形成的CNT网络具有巨大的潜力,可以利用直流测量来开发传感以进行损坏检测和健康监测。施加在纳米掺杂粘合剂上的负载会在材料中产生损坏(即裂缝,分层等)和/或损坏进展,从而改变碳网络的完整性并增加粘合剂的电阻率。已经开发出两种不同的方法将CNT沉积在薄膜胶粘剂上:创新的喷墨印刷方法和掩模方法。在这两种情况下,所使用的CNT均在水溶液中稳定,以使用不会破坏胶粘剂性能的溶剂。然后,将碳纳米管溶液结合到纳米增强材料中,并在薄膜上形成可控制的几何形状,从而对结合的接头提供局部和可控制的敏感性,并以准确的方式提供损伤位置,特征及其传播的信息。

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