Development of Modelling and Testing for Analysis of Degradation in Solid Oxide Fuel Cells

摘要

The ability to predict the lifetime performance of an SOFC can give guidelines for where improvements and alterations can be made in terms of production, operating parameters and cell design. This study focuses on continuous degradation mechanisms and the impact they have on the components of a single repeating unit level, i.e. the anode, cathode, electrolyte, metal interconnect and sealants. Currently the model being developed deals specifically with anode and electrolyte degradation. Depending on operating conditions, SOFC cells suffer from Ni particle agglomeration, coarsening, and volatilisation which lead to increased overpotential in the anode. A loss in the ionic conductivity in the electrolyte is also observed. Matlab coding has been developed to outline the loss of performance in a single repeating unit for a given set of operating parameters. These equations will be tested against real life data to establish their validity and, where necessary, adjusted for accuracy.