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Parametric sensitivity analysis for a natural gas fueled high temperature tubular solid oxide fuel cell

机译:天然气燃料高温管状固体氧化物燃料电池的参数敏感性分析

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摘要

For more than the last two decades, there has been research going on to develop advanced energy technologies involving minimum environmental pollution, to replace the conventional fossil energy systems. Solid oxide fuel cells (SOFCs) are one of the most promising, eco-friendly and efficient means for the generation of electricity to meet the future energy requirements. This research work focuses on the parametric sensitivity analysis for natural gas fueled high temperature tubular SOFC. Firstly, for the tubular SOFC, a one-dimensional radially symmetrical model has been developed and solved using the finite-difference method. Then, the effect of the variation of important operational and design parameters on its performance has been analyzed. The parameters typically include composition, inlet fuel temperature, pressure, length of SOFC tube and thicknesses of its components. The composition is expressed as steam to methane ratio and it has been observed that the voltage and power density developed by the SOFC diminishes as the ratio increases. Further, a change in the inlet fuel pressure of the tubular SOFC has no pronounced influence on the voltage and power density developed. On the other hand, with an increase in the inlet fuel temperature, a small improvement in these performance characteristics is exhibited. The axial length of the tubular SOFC does conspicuously influence its performance characteristics but solely at current densities greater than 4000A/m2. An increase in the thickness of its components results in a reduction in its voltage and power density developed. The largest decline in these performance characteristics with the increase in thickness is observed for electrolyte followed by cathode and anode respectively.
机译:对于过去二十年来,有研究开发涉及最低环境污染的先进能源技术,以取代传统的化石能源系统。固体氧化物燃料电池(SOFC)是最有希望,生态友好的有效的手段之一,用于符合未来的能源需求。该研究工作侧重于天然气燃料高温管状SOFC的参数敏感性分析。首先,对于管状SOFC,已经使用有限差分方法开发和解决了一维径向对称模型。然后,分析了重要操作和设计参数变化对其性能的影响。参数通常包括组成,入口燃料温度,压力,SOFC管的长度和其组分的厚度。该组合物表示为蒸汽与甲烷的比率,并且已经观察到由于比率增加,由SOFC产生的电压和功率密度减小。此外,管状SOFC的入口燃料压力的变化对电压和功率密度没有明显的影响。另一方面,随着入口燃料温度的增加,表现出这些性能特征的小改善。管状SOFC的轴向长度明显地影响其性能特性,但仅在大于4000A / m 2的电流密度下。其组件厚度的增加导致其电压和功率密度的降低。观察到厚度增加的这些性能特征的最大下降分别用于电解质,然后分别观察到阴极和阳极。

著录项

  • 期刊名称 Heliyon
  • 作者单位
  • 年(卷),期 2020(6),7
  • 年度 2020
  • 页码 e04450
  • 总页数 11
  • 原文格式 PDF
  • 正文语种
  • 中图分类
  • 关键词

    机译:化学工程;化学;环境科学;固体氧化物燃料电池(SOFC);参数敏感性;三相边界(TPB);开路电压(OCV);功率密度;电流密度;电流密度;电流密度;
  • 入库时间 2022-08-21 12:16:13

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