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Influence of Hollow Cathode Plasma on AITiSiN-Thin Film Deposition with Vacuum Arc Evaporation Sources

机译:空心阴极等离子体对真空电弧蒸发源AITiSiN薄膜沉积的影响

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In the past the plasma assisted AlTiN and AlCrN thin film deposition had been carried out by means of simultaneous operation of hollow cathode with vacuum arc evaporation sources. The additional hollow cathode plasma (P~+- technology) results in advanced thin film properties such as higher hardness, lower droplet density and improved wear resistance. Although, by the addition of silicon to AlTiN or AlCrN standard vacuum arc coatings a phase separation, and the forming of nanocomposites TiAIN / Si_3N_4 - or AlCrN / Si_3N_4 coatings with super hardness and excellent temperature stability were reported, the goal of the presented application of the newly developed P~+- technology is to further improve the deposition conditions as well as to optimize the AlTiSiN thin film properties. A comparison of AlTiSiN thin film coatings deposited by standard vacuum arc sources and the P~+ - process will be presented. AlTiSi target materials with three different contents of silicon (5, 10 and 15 at %) were used for the thin film deposition. The effects of modified silicon contents in AlTiSi- target materials and the simultaneous operation of the two hollow cathodes on plasma parameters during the vacuum arc coating process were examined by the use of optical emission spectroscopy (OES). The influence of the measured plasma parameters on selected AlTiSiN thin film properties will be demonstrated in the standard as well as in the P~+- process.
机译:过去,借助于空心阴极与真空电弧蒸发源的同时运行,进行了等离子体辅助的AlTiN和AlCrN薄膜沉积。附加的空心阴极等离子体(P〜+-技术)可实现先进的薄膜性能,例如更高的硬度,更低的墨滴密度和更高的耐磨性。尽管通过向AlTiN或AlCrN标准真空电弧涂层中添加硅进行了相分离,并形成了具有超高硬度和优异的温度稳定性的纳米复合材料TiAIN / Si_3N_4-或AlCrN / Si_3N_4涂层,但该报告提出的应用目标是新开发的P〜+-技术将进一步改善沉积条件并优化AlTiSiN薄膜的性能。将比较标准真空电弧源和P〜+-工艺沉积的AlTiSiN薄膜涂层。具有三种不同硅含量(5、10和15 at%)的AlTiSi目标材料用于薄膜沉积。通过使用光发射光谱法(OES)检验了AlTiSi靶材料中改性的硅含量以及两个空心阴极在真空电弧镀膜过程中同时操作对等离子体参数的影响。在标准以及P〜+-工艺中将证明所测得的等离子体参数对所选AlTiSiN薄膜性能的影响。

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