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Glyoxylase biomimics: zeolite catalyzed conversion of trioses

机译:乙醛酸酶的仿生物:沸石催化的三糖的转化

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Direct conversion of biomass derived trioses such as dihydroxyacetone (DHA) and glyceraldehyde (GLA) to alkyl lactates was carried out using alcohols over various Y type zeolite materials. The conversion takes place through a pyruvic aldehyde intermediate which subsequently undergoes esterification. The screened catalysts can be grouped based on their ability to either form methylglyoxal dialkyl acetal or alkyl lactate. The discussed catalysis shows strong resemblance with the biological lactic acid synthesis routes where glyoxylases effect the reaction. Zeolites may therefore be considered as functional biomimics of these enzymes.
机译:使用醇在各种Y型沸石材料上将生物质衍生的三糖如二羟基丙酮(DHA)和甘油醛(GLA)直接转化为烷基乳酸酯。转化通过丙酮醛中间体进行,其随后进行酯化。可以基于它们形成甲基乙二醛二烷基乙缩醛或乳酸烷基酯的能力对筛选的催化剂进行分组。所讨论的催化显示出与乙二醛酶影响反应的生物乳酸合成路线的相似性。因此,沸石可以被认为是这些酶的功能仿生物。

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