THEORETICAL PREDICTION OF THERMAL DIFFUSION COEFFICIENTS FOR TERNARY HYDROCARBON MIXTURES BASED ON THE IRREVERSIBLE THERMODYNAMICS THEORY

摘要

An accurate thermodiffusion model is of paramount importance to the petroleum industry for the prediction of the compositional variation in hydrocarbon reservoirs. Several theoretical models have been developed. Kempers and Firoozabadi models are the latest two models, which are not only applicable for binary mixtures but also for multicomponent mixtures. In this paper, we applied the Firoozabadi model to a ternary hydrocarbon mixture of dodecane, n-butane and methane with different mass fraction. It reveals that the accuracy of the thermal diffusion coefficients for a specific mixture of interest relies on the accuracy of the thermodynamic properties from equations of state, corresponding Fick's diffusion coefficients, and the thermal diffusion modeling.