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Hydrogen diffusionin boron-doped diamond: evidence of hydrogen-boron interactions

机译:氢在掺硼金刚石中的扩散:氢-硼相互作用的证据

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Deuterium diffusion has been investigated in boron doped diamond as a function of the diffusion temperature and the boron concentration. The results show that, up to 480 deg, hydrogen diffusion is limited by the boron concentration with a diffusion activation energy of 0.35 eV for [B]=5x10~(19) cm~(-3). This first experimental evidence of deuterium-boron interactions in dimaond is interpreted as teh result of hydrogen ionization and diffusion of fairly mobile protons which form pairs with negatively charged boron acceptors.
机译:已经研究了掺硼金刚石中氘的扩散与扩散温度和硼浓度的关系。结果表明,在[B] = 5x10〜(19)cm〜(-3)时,氢的扩散受硼浓度限制,直至480度,扩散活化能为0.35 eV。氘代硼与硼相互作用的第一个实验证据被认为是氢离子化和相当易移动的质子扩散的结果,质子与带负电的硼受体形成对。

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