The present invention relates to an all-solid-state iron-air battery, which comprises a positive electrode, a negative electrode, a separator and a solid electrolyte, wherein the positive electrode and the negative electrode are respectively arranged on opposite sides of the solid electrolyte; the separator is arranged between the negative electrode and the solid electrolyte to form a sandwich structure; the negative electrode is a ferrate material formed from an alkali metal-doped iron oxide; the positive electrode is a metal or a metal oxide material with an efficient redox catalytic activity; the solid electrolyte is an electrolyte material capable of efficiently conducting oxygen ions; and the separator is a film-like or sheet-like material having oxygen ion conduction and electronic insulation performances. According to the all-solid-state iron-air battery of the present invention, in the negative electrode, by introducing the alkali metal into an iron oxide crystal lattice by means of doping, the electrochemical reaction activity of the iron electrode can be remarkably improved, the potential safety hazard problem caused by battery overcharging is improved, and the performance of the iron-air battery is remarkably improved; and the separator is arranged between the solid electrolyte and the negative electrode, such that the battery electric leakage problem can be effectively relieved.
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