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HIGH-COMPACTED-DENSITY POSITIVE ELECTRODE MATERIAL AND ELECTROCHEMICAL ENERGY STORAGE APPARATUS

机译:高压缩密度正极材料和电化学储能设备

摘要

This application relates to the field of battery technologies, and in particular, to a high-compacted-density positive electrode material and an electrochemical energy storage apparatus. The positive electrode material includes a lithium-nickel transition metal oxide A and a lithium-nickel transition metal oxide B. The lithium-nickel transition metal oxide A is secondary particles, whose chemical formula is shown in formula I: Lia1(Nib1Coc1Mnd1)x1M1-x1O2-e1Xe1. The lithium-nickel transition metal oxide B is a monocrystalline structure or a monocrystalline-like structure, whose chemical formula is shown in formula II: Lia2(Nib2Coc2Mnd2)x2M′1-x2O2-e2X′e2 (II). The positive electrode material of this application includes the large-particle lithium-nickel transition metal oxide A and the small-particle lithium-nickel transition metal oxide B to improve an energy density of the battery. A degree of crystallinity and particle size distribution of the mixed positive electrode material can improve a compacted density of the high-nickel active material, and ensure lower gassing and good cycle performance.
机译:本申请涉及电池技术领域,尤其涉及高压实密度正电极材料和电化学能量存储装置。正极材料包括锂 - 镍过渡金属氧化物A和锂 - 镍过渡金属氧化物B.锂 - 镍过渡金属氧化物A是二次颗粒,其化学式在式I中示出:Li A1 < / sub>(Ni b1 co <​​sub> c1 mn d1 x1 m 1-x1 O 2-e1 x e1 。锂 - 镍过渡金属氧化物B是单晶结构或单晶相实的结构,其化学式在式II中示出:Li A2 (Ni B2 Co C2 Mn d2 x2 m' 1-x2 o 2-e2 x'<亚> E2 (ii)。该应用的正极材料包括大颗粒锂 - 镍过渡金属氧化物A和小颗粒锂 - 镍过渡金属氧化物B,以改善电池的能量密度。混合正极材料的结晶度和粒度分布可以提高高镍活性材料的压实密度,并确保降低气相和良好的循环性能。

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