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UV-CURING ACRYLIC RESIN COMPOSITIONS FOR THERMOFORMABLE HARD COAT APPLICATIONS

机译:用于热可铸造硬涂层应用的UV固化丙烯酸树脂组合物

摘要

The present invention provides a thermoformable and optically clear hard coat comprising a polyacrylate resin and 5 wt. % or less of inorganic nanoparticles with an average particle size of 100 nm or less in diameter based on total weight of resin solid. The polyacrylate resin is derived from polymerizing and curing ultraviolet (UV) curing acrylic compositions for use in making thermoformable hard coats for curved optical displays comprising (a) from 9 to 70 wt. %, based on the total weight of monomer solids, of an aliphatic tetrafunctional (meth)acrylate monomer or an aliphatic pentafunctional (meth)acrylate monomer; (b) from 3 to 30 wt. %, based on the total weight of monomer solids, of one or more one (meth)acrylate monomer containing an isocyanurate group; (c) from 5 to 55 wt. %, based on the total weight of monomer solids, of one or more aliphatic urethane (meth)acrylate functional oligomer having from 6 to 24 (meth)acrylate groups; (d) from 2 to 10 wt. %, based on total monomer solids, of one or more UV radical initiators; (e) from 10 to 30 wt. %, based on the total weight of (a), (b), (c), and (d), of one or more sulfur-containing polyol (meth)acrylates; and (f) one or more organic solvents for the monomer composition.
机译:本发明提供一种热可变和光学透明的硬涂层,其包含聚丙烯酸酯树脂和5wt。基于树脂固体的总重量,直径为100nm或更小的平均粒径的%或更少的无机纳米颗粒。聚丙烯酸酯树脂衍生自聚合和固化紫外线(UV)固化丙烯酸组合物,其用于制造热可变的硬涂层,用于弯曲的光学显示器,其包括从9至70wt的曲线显示器。 %,基于单体固体的总重量,脂族四官能(甲基)丙烯酸酯单体或脂族五官能(甲基)丙烯酸酯单体; (b)从3到30重量%。基于含有异氰脲酸酯基团的一种或多种(甲基)丙烯酸酯单体的单体固体的总重量%; (c)5至55重量%。基于单体固体的总重量,具有6至24个(甲基)丙烯酸酯基团的一种或多种脂族氨基甲酸酯(甲基)丙烯酸酯的官能低聚物; (d)2至10重量%。 %,基于一个或多个UV自由基引发剂的总单体固体; (e)从10到30重量%。 %,基于(a),(b),(c)和(d)的总重量,其一种或多种含硫多元醇(甲基)丙烯酸酯; (f)单体组合物的一种或多种有机溶剂。

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