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Process for the removal of the consisting of stainless steel to optionally servings nsta ends, in particular to uranium - core fuel elements

机译:去除不锈钢成分至可选的nsta末端,特别是铀-核心燃料元件的方法

摘要

Stainless steel is removed from a stainless steel clad body by intimately contacting the body with a gaseous stream containing oxygen and solid metal fluoride particles. In the preferred embodiment, a stainless steel clad body such as a stainless steel clad uranium bearing fuel element is immersed in a fluidized bed of which 1% by weight of the bed particles are aluminium fluoride and the remainder aluminium oxide. The bed is activated by intimately contacting and fluidizing the bed particles with fluorine at a temperature between 400 DEG C. and 450 DEG C. for a period of up to half an hour, whereupon the bed is fluidized and the element immersed therein intimately contacted with oxygen at a temperature between 675 DEG C. and 750 DEG C. until the desired degree of decladding is achieved. The steel cladding is often found to split, perforate or rupture during the decladding leaving the uranium exposed for immediate recovery. Fluorine is then passed through the bed to intimately contact the exposed uranium and convert it into uranium hexafluoride which after being passed through filters is condensed and further treated by conventional means to recover the uranium therefrom. The bed is fluidized by fluorine in this latter stage under the same conditions as in the first stage so that the bed particles are again activated and the bed is ready to receive another fuel element for decladding. In the preferred embodiment, the fluorine makes up 25% by volume of a mixture with argon, this mixture being used because of the high reactivity of fluorine, whereas the oxygen used is 100% pure.
机译:通过使不锈钢与覆层的主体与包含氧气和固态金属氟化物颗粒的气流紧密接触,从而将其从不锈钢覆层主体中去除。在优选的实施方案中,将不锈钢复合体例如含不锈钢复合铀的燃料元件浸入流化床中,其中流化床的1重量%是氟化铝,其余是氧化铝。通过在400℃至450℃之间的温度下使床颗粒与氟紧密接触并使其流化达半小时,从而活化该床,然后使该床流化并且将浸入其中的元素与之紧密接触。在675℃和750℃之间的温度下通入氧气直到达到所需的脱壳程度。通常在覆层过程中发现钢覆层开裂,穿孔或破裂,铀暴露出来可立即回收。然后使氟通过该床以与暴露的铀紧密接触,并将其转化成六氟化铀,该六氟化铀在通过过滤器后被冷凝,并通过常规方法进一步处理以从中回收铀。在后面的步骤中,在与第一阶段相同的条件下,床层被氟流化,以使床层颗粒再次被活化,并且床层准备好接受另一个用于脱壳的燃料元件。在优选的实施方案中,氟占与氩的混合物的25体积%,使用该混合物是因为氟的高反应性,而所用的氧气是100%纯的。

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