首页> 外国专利> Selective herbicide contg. a phenoxy-phenoxy-propionic acid deriv. - and a herbicide antidote e.g. N,N-di:allyl-di:chloro:acetamide

Selective herbicide contg. a phenoxy-phenoxy-propionic acid deriv. - and a herbicide antidote e.g. N,N-di:allyl-di:chloro:acetamide

机译:选择性除草剂续。苯氧基-苯氧基-丙酸衍生物。 -和除草剂解毒剂,例如N,N-二:烯丙基-二:氯:乙酰胺

摘要

In selectively combatting weeds in maize, rice and other cereal cultures, the seeds, the soil intended for sowing, or culture surfaces which have been sown or are occupied by plants is/are treated simultaneously or successively with a herbicide of formula (I) and an antidote of formulae (II), (III) or (IV). In the formulae, R1 is H, F, Cl, Br, I or CF3; R2 is H or Cl; R3 is OR, OM, NH2, NH(lower alkyl) or N(lower alkyl)2; R is H or 1-10C alkyl; M is an equiv. of an (in)organic cation; R'1 is H, 1-5C alkyl (opt. halogenated or substd. by CN or 3-6C cycloalkyl), 3-5C alkenyl or alkynyl, or opt. halogenated is not 6C alkoxyalkyl, dialkoxyalkyl or alkenyloxyalkyl; R'2 is 1-5C alkyl (opt. halogenated or substd. by CN or 3-6C cycloalkyl), 3-5C alkenyl or alkynyl, opt. halogenated is not 6C alkoxyalkyl, dialkoxyalkyl or alkenyloxyalkyl, or opt. vinyl- or ethynyl-substd. 3-6C cycloalkyl; or NR'1R'2 is 5- to 7-membered heterocycle opt. additionally contg. an O-, N- or S-atom and/or mono- or poly-substd. by lower alkyl; R"1 is H or is not 5C alkenyl or alkyl; R"2 is not 6C alkyl, alkenyl or alkynyl, is not 6C dialkoxyalkyl, or opt. vinyl- or ethynyl-substd. 3-6C cycloalkyl; or RR"1R"2 is heterocycle opt. contg. a further N-, O- or S-atom and/or mono- or poly-substd. by lower alkyl; n = 1,2,3,4,5 or 6; R1 is opt. halo-substd. =6C alkyl, acetoxy-(lower alkyl), acetoxy-(halo lower alkyl) or aryl; and X is Cl or Br. The antidotes (II), (III) and (IV) unexpectedly increase the selectivity of the herbicides (I), which are active against grasses.
机译:在玉米,水稻和其他谷物栽培中选择性防治杂草时,将种子,拟播种的土壤或已播种或被植物占用的培养表面同时或依次用式(I)除草剂处理。式(II),(III)或(IV)的解毒剂。式中,R 1为H,F,Cl,Br,I或CF 3; R 2为H或Cl; R3是OR,OM,NH2,NH(低级烷基)或N(低级烷基)2; R为H或1-10C烷基; M是当量。一个有机阳离子; R′1是H,1-5C烷基(被CN卤代或被3-6C环烷基取代或取代),3-5C烯基或炔基,或opt。卤代不是> 6C的烷氧基烷基,二烷氧基烷基或烯基氧基烷基; R′2是1-5C烷基(被CN或3-6C环烷基卤代或取代),3-5C烯基或炔基。卤代的不是> 6C的烷氧基烷基,二烷氧基烷基或烯基氧基烷基,或opt。乙烯基或乙炔基取代。 3-6C环烷基;或NR'1R'2是5至7元杂环选择。另外续。 O,N或S原子和/或单或多取代基。通过低级烷基; R” 1是H或不是> 5C的烯基或烷基; R” 2不是> 6C的烷基,烯基或炔基,不是> 6C的二烷氧基烷基或opt。乙烯基或乙炔基取代。 3-6C环烷基;或RR“ 1R” 2是杂环opt。续另外的N,O或S原子和/或单或多取代基。通过低级烷基; n = 1,2,3,4,5或6; R1是可选的。晕晕的= 6C烷基,乙酰氧基-(低级烷基),乙酰氧基-(卤代低级烷基)或芳基; X为Cl或Br。解毒剂(II),(III)和(IV)出乎意料地提高了对草有活性的除草剂(I)的选择性。

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