Aqueous dispersions of copolymers of acrylic esters, tertiary, their process of preparation and their use, in particular for the manufacture of products adhesives

摘要

1521716 Aqueous dispersion of polymers based on non-tertiary allyl acrylates BASF AG 12 Dec 1975 [14 Dec 1974] 50975/75 Heading C3P A polymer made up of, by weight (a) 70- 90% of a non-tertiary C8 alkyl acrylate, (b) 4-12% of methyl methacrylate, (c) 4-12% of a vinyl ester of a C2-4 carboxylic acid, (d) 1- 5% of acrylonitrile, (e) 0À5-3% of a hydroxy C2-5 alkyl (meth)acrylate, and (f) 0À5-3% of an alpha,#-olefinically unsaturated mono- or di-carboxylic acid or a monoester of such a dicarboxylic acid, is prepared by conventional emulsion polymerization to a K value of 74 to 90 in aqueous medium containing as emulsifying agent a sulphated and alkoxylated fatty alcohol, fatty amine or alkyl phenol. Component (a) may also contain other non-tertiary alkyl acrylates whose homopolymers have glass temperatures below -30‹ C. and component (f) may also contain vinyl sulfonic acid or a salt thereof. Uses.- As pressure sensitive adhesives when coated on a suitable backing.