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DEUTERIUM ENRICHMENT BY SELECTIVE PHOTO-INDUCED DISSOCIATION OF AN ORGANIC CARBONYL COMPOUND

机译:选择性羰基分解有机羰基化合物富集氘

摘要

ABSTRACT OF THE DISCLOSUREA method for producing a deuterium enriched mate-rial by photo-induced dissociation which uses as the work-ing material a gas phase photolytically dissociable organ-ic carbonyl compound containing at least one hydrogen atombonded to an atom which is adjacent to a carbonyl groupand consisting of molecules wherein said hydrogen atom ispresent as deuterium and molecules wherein said hydrogenatom is present as another isotope of hydrogen. The or-ganic carbonyl compound is subjected to intense infraredradiation at a preselected wavelength to selectively ex-cite and thereby induce dissociation of the deuterium con-taining species to yield a deuterium enriched stable mo-lecular product. Undissociated carbonyl compound, depletedin deuterium, is preferably redeuterated for reuse.
机译:披露摘要一种生产氘富集材料的方法通过光致离解而进行的里亚尔物质是气相可光解离的器官含至少一个氢原子的ic羰基化合物键合至与羰基相邻的原子并且由其中所述氢原子为作为氘和分子存在,其中所述氢原子作为氢的另一种同位素存在。或羰基有机化合物经受强红外以预先选择的波长辐射,以选择性地引用并由此诱导氘缩合的解离产生氘富集的稳定Mo-世俗的产品。未解离的羰基化合物,已耗尽在氘气中,最好重新进行氘化以重复使用。

著录项

  • 公开/公告号CA1110199A

    专利类型

  • 公开/公告日1981-10-06

    原文格式PDF

  • 申请/专利权人 US ENERGY;

    申请/专利号CA19790324092

  • 发明设计人 MARLING JOHN B.;

    申请日1979-03-26

  • 分类号B01J1/10;

  • 国家 CA

  • 入库时间 2022-08-22 15:44:05

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