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PROCESS AND INSTALLATION FOR OBTAINING ETHANOL BY THE CONTINUOUS ACID HYDROLYSIS OF CELLULOSIC MATERIALS

机译:连续酸水解纤维素材料制取乙醇的工艺及安装

摘要

Invention patent for a "Process and Installation for Obtaining Ethanol by the Continuous Acid Hydrolysis of Cellulosic Materials", such process comprising the stages of: providing an homogenized aqueous pulp of cellulosic material having 3 to 30% in weight of solids; pumping the cellulosic material pulp, in a substantially continuous way, to the interior of the inlet end of a tubular reactor and restricting its outlet opposite end to maintain a given internal pressure inside the same; heating the pressurized cellulosic material pulp up to the temperature of about 160 DEG to 250 DEG C. before its introduction into the reactor; adding, in a substantially continuous way, a given dose of a concentrated acid to the pressurized and heated cellulosic material pulp, which will be continuously diluted in the reactor, to provide the hydrolysis reaction of said pulp, the acid addition being made inside the reactor at a point longitudinally adjustable from the inlet end of the reactor; discharging in a substantially continuous way through the outlet end of the reactor a given load of hydrolyzed cellulosic material, said discharge being regulated in conjunction with the longitudinal positioning of the point of addition of the acid, thus fixing the reaction time adequate for the cellulosic material pulp; subjecting the hydrolyzed cellulosic material pulp to an abrupt pressure drop and cooling immediately after it leaves the reactor; neutralizing and fermenting the resulting aqueous solution to obtain ethanol; and recovering the resulting byproducts which are methanol, furfural, acetic acid and lignin.
机译:“通过纤维素材料的连续酸水解获得乙醇的方法和装置”的发明专利,该方法包括以下步骤:提供均质的纤维素材料的均质含水浆,其固体含量为3%至30%;以基本连续的方式将纤维素材料浆泵送到管式反应器入口端的内部,并限制其出口的另一端,以保持其内部给定的内部压力;在将加压的纤维素材料纸浆引入反应器之前,将其加热至约160-250℃的温度。以基本上连续的方式向加压和加热的纤维素材料纸浆中添加一定剂量的浓酸,将其在反应器中连续稀释,以提供所述纸浆的水解反应,酸的添加在反应器内部进行从反应器进口端可纵向调节的位置;通过反应器的出口端以基本上连续的方式排出一定量的水解纤维素材料,所述排出与酸添加点的纵向位置相关联地进行调节,从而固定了适合纤维素材料的反应时间纸浆;使水解的纤维素材料浆在离开反应器后立即经受突然的压降并冷却;中和并发酵得到的水溶液以获得乙醇;并回收所得的副产物,它们是甲醇,糠醛,乙酸和木质素。

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