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PROTECTION FROM ULTRAVIOLET RAYS USING NOVEL ULTRAVIOLET LIGHT ABSORBER
PROTECTION FROM ULTRAVIOLET RAYS USING NOVEL ULTRAVIOLET LIGHT ABSORBER
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机译:使用新型紫外线吸收剂保护紫外线
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摘要
PURPOSE:To obtain a photostabilized polmer composition highly resistant to heat and oxidation, free from bleeding out, having been prevented from deterioration by shielding ultraviolet light, by incorporating a cyclic imino ester as an ultraviolet light absorber in a polymer of high melting point. CONSTITUTION:The objective composition can be obtained by incorporating (A) 100pts.wt. of a polymer (e.g., a thermoplastic resin) with (B) as an ultraviolet light absorber, pref. 0.05-5pts.wt. of a compound in the form of unreacted condition, selected from cyclic imino esters of formula I (X' is a divalent aromatic group; n is 1, 2 or 3; R1 is n-valent hydrocarbon) or formula II (A is expressed by formula III or IV; R2 and R3 are each monovalent hydrocarbon; X2 is a tetravalent aromatic group) [e.g., 2-methyl-3,1-benzoxazine-4-one or 2,8-dimethyl- 4H,6H-benzo (1,2-d; 5,4-d')bis-(1,3)-oxazine-4,6-dione], followed by kneading under molten state.
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机译:用途:通过在高熔点聚合物中掺入环状亚氨基酯作为紫外线吸收剂,从而获得一种对热和氧化具有高度抵抗力的光稳定化的聚合物组合物,从而不会渗出,并且通过屏蔽紫外线来防止变质。组成:可以通过掺入(A)100pts.wt获得目标组成。 (B)作为紫外线吸收剂的聚合物(例如热塑性树脂)的制备。 0.05-5pts.wt。选自式I的环状亚氨基酯(X'为二价芳族基团; n为1、2或3; R 1为n价烃)的未反应条件形式的化合物的化合物由式III或IV表示; R 2和R 3各自为一价烃; X 2为四价芳族基团] [例如2-甲基-3,1-苯并恶嗪-4-酮或2 1,8-二甲基-4H,6H-苯并(1,2-d; 5,4-d')双-(1,3)-恶嗪-4,6-二酮],然后在熔融状态下捏合。
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