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Process for manufacturing a catalyst containing iron, chromium and potassium oxides and at least one rare earth metal oxide, for use in dehydrogenation reactions

机译:用于脱氢反应的包含铁,铬和钾的氧化物和至少一种稀土金属氧化物的催化剂的制造方法

摘要

A process for manufacturing catalysts containing, as oxides, iron, chromium, potassium, as well as a rare earth metal in a proportion, calculated in oxide weight, of 1-15% with respect to the final catalyst, comprises:PPa first step, wherein a product is prepared by a reaction between compounds of rare earth metal(s) and of another metal selected from Fe, Cr, Co, Al or V, and a calcination; andP Pa second step wherein a mixture is formed between the product resulting from the first step, the other necessary reactants and water; the resulting paste is dried after optional shaping and calcined. A clayish material can be used in the step.PPThe catalysts obtained present an improved efficiency in dehydrogenation reactions, particularly of ethylbenzene to styrene.
机译:用于生产包含作为氧化物的铁,铬,钾和稀土金属的氧化物的催化剂的方法,该氧化物的重量相对于最终催化剂为1-15%,包括: P>第一步,其中通过使稀土金属与选自Fe,Cr,Co,Al或V的另一种金属的化合物之间的反应和煅烧来制备产物;第二步,在第一步产生的产物,其他必要的反应物和水之间形成混合物。可选的成型后将得到的糊状物干燥并煅烧。该步骤中可以使用粘土材料。所获得的催化剂在脱氢反应,特别是乙苯到苯乙烯的脱氢反应中具有改进的效率。

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