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process for the production of spherical particles of active alumina with high mechanical strength

机译:机械强度高的活性氧化铝球形颗粒的制备方法

摘要

Strong spherical granules of active alumina are prepd. by granulating a mixt. of an aluminium oxide hydrate (opt. preliminary dehydrated and ground) and carbon with addn. of an ammonia soln.; drying the granules; heating them at 250-500 degrees C; and finally calcining at 1000-1200 degrees C. The granulation is carried out with addn. of long-chain aliphatic cpds. and/or clay. The granular alumina can be impregnated with a catalyst soln. and used as a mobile catalytic bed; the mechanical strength and abrasion resistance of the granules is very high. The addn. of the long-chain aliphatic cpds. diminished the width of the particle size spectrum, whilst the ave. size can be adjusted to the reqd. value by known methods. The addn. of clay improves the workability of the mixt. of starting matls., reduces the bulk density of the prod. (by 0.15-0.20 kg/l) and increases its specific surface area (by 30-70 m2/g).
机译:制备活性氧化铝的强球形颗粒。通过将混合物制粒氧化铝水合物(经初步脱水和研磨)和碳与加成物。氨溶液;干燥颗粒;在250-500摄氏度下加热它们;最后在1000-1200℃下煅烧。制粒用addn进行。长链脂肪族cpds。和/或黏土。粒状氧化铝可以用催化剂溶液浸渍。用作移动催化床;颗粒的机械强度和耐磨性非常高。地址。长链脂肪族cpds减小了粒径谱的宽度,而ave减小了。大小可以调整到要求。通过已知方法获得价值。地址。粘土的使用改善了混合物的可加工性。起始原料的数量减少,降低了产品的堆积密度。 (增加0.15-0.20千克/升),并增加其比表面积(增加30-70平方米/克)。

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