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METHOD FOR PRODUCING A POLYMERIZATION CATALYST AND PRODUCING AETHYLENE POLYMERS WITH THIS CATALYST.

机译:制备聚合催化剂和用该催化剂制备乙烯聚合物的方法。

摘要

Process for preparing and treating a chromium-containing catalyst so that when the catalyst is activated the risk of explosion is substantially reduced. The catalyst comprises a complex of chromium and optionally other transition metal complexes reacted with one or more organometallic compounds of a metal of group II or III of the periodic table, which metal contains hydrocarbyl groups of 1-20 carbon atoms. The reaction product is applied to an inert inorganic support to form the catalyst component which is deactivated by treatment with oxygen or an alcohol to modify or replace residual hydrocarbyl groups. The catalyst component may be activated to form the catalyst by heating in the range 200 DEG -1200 DEG C. The catalyst is used to catalyze a polymerization of alpha-olefins.
机译:制备和处理含铬催化剂的方法,使得当催化剂活化时,爆炸的风险大大降低。该催化剂包含铬的络合物和任选的其他过渡金属络合物,其与周期表II或III族金属的一种或多种有机金属化合物反应,该金属含有1-20个碳原子的烃基。将反应产物施加到惰性无机载体上以形成催化剂组分,该催化剂组分通过用氧气或醇处理以改性或替代残留的烃基而失活。催化剂组分可以通过在200℃-1200℃范围内加热而活化,以形成催化剂。该催化剂用于催化α-烯烃的聚合。

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