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TREATMENT OF RESIDUAL ZIEGLER CATALYST IN POLYMERS WITH ALCOHOL

机译:醇处理聚合物中残留的齐格勒催化剂

摘要

Polymer resins prepared by polymerizing alpha-olefins in the presence of high activity Ziegler and/or Ziegler-Natta polymerization catalyst compositions are treated with at least one alcohol of the formula R'' - OH wherein R'' is a C1-C10 alkyl, alkenyl, aryl, alkaryl or aralkyl group. The alcohol must be used in the vapor phase. The treatment with the alcohol eliminates the odor and discoloration of the products, especially injection molded products, produced from the resins.
机译:通过在高活性齐格勒和/或齐格勒-纳塔聚合催化剂组合物存在下聚合α-烯烃制得的聚合物树脂用至少一种式R''-OH的醇处理,其中R''为C1-C10烷基,烯基,芳基,烷芳基或芳烷基。酒精必须以气相使用。用醇处理消除了由树脂生产的产品特别是注塑产品的气味和变色。

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