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Electrophotographic multi-layered photosensitive member having a top layer of amorphous silicon carbine and method for fabricating the same

机译:具有非晶硅卡宾顶层的电子照相多层感光构件及其制造方法

摘要

An electrophotographic multi-layered photosensitive member comprises a top layer (11) of hydrogenated amorphous silicon carbide formed over a photoconductive layer (3) and having an atomic ratio of carbon to carbon plus silicon C/(Si+C) ranging from 0.17 to 0.45 and a ratio of number of hydrogen atoms bonded to silicon atoms per silicon atom, to number of hydrogen atoms bonded to carbon atoms per carbon atom, (Si-H)/Si / (C-H)/C , ranging from 0.3 to 1.0. The top layer is formed on a photosensitive layer of hydrogenated amorphous silicon by employing a glow discharge CVD method. In one embodiment, the gaseous mixture is composed of disilane (Si₂H₆) and propane (C₃H₈) mixed with a mol ratio C₃H₈/(Si₂H₆+ C₃H₈) ranging from 0.2 to 0.6. In another embodiment, the gaseous mixture comprises disilane (Si₂H₆) gas, propane (C₃H₈) gas, and hydrogen (H₂) gas, the mixing mol ratio C₃H₈/ (Si₂H₆+C₃H₈) ranging from 0.2 to 0.7, and the mixing mol ratio H₂/(Si₂H₆+C₃H₈ ranging froml 1 to 10.
机译:电子照相多层感光构件包括在光导层(3)上形成的氢化非晶碳化硅顶层(11),其碳原子比碳原子+硅C /(Si + C)的原子比为0.17至0.45每个硅原子与硅原子键合的氢原子数与每个碳原子与碳原子键合的氢原子数之比(Si-H)/ Si /(CH)/ C为0.3至1.0。通过采用辉光放电CVD法在氢化非晶硅的感光层上形成顶层。在一个实施方案中,气体混合物由乙硅烷(Si 2 H 4)和丙烷(C 3 H 4)组成,摩尔比C 4 H 6 /(Si 2 H 4 + C 4 H 5)混合。在另一个实施方案中,气体混合物包括乙硅烷(Si 2 H 4)气,丙烷(C​​ 3 H 4)气和氢气(H 2)气,混合摩尔比C 3 H 4 /(Si 2 H 4 + C 3 H 4)为0.2至0.7,混合摩尔比H 2 /(Si 2 H 3 + C 3 H 4的范围为1至10。

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