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BASIC METAL-ZEOLITE COMPOSITIONS,THEIR PREPARATION AND USE IN BASE CATALYZED REACTIONS

机译:碱性金属沸石组合物,其制备及其在碱催化反应中的应用

摘要

Basic compositions comprising a zeolite and one or more metal compounds of Group IA, IIA, the Transition Metals or the Rare Earth Metals wherein the sum of the amount of the metal compound(s) in said compound(s) and any metal cation exchanged into the zeolite is in excess of that required to provide a fully metal cation-exchanged zeolite. The basic compositions can be suitably applied in base catalyzed reactions such as the double bond isomerization of olefins, the alkylation of aromatic compounds and the oxidative production of primary alkanols and/or aldehydes from paraffins.
机译:包含沸石和一种或多种IA,IIA组金属化合物,过渡金属或稀土金属的基本组合物,其中所述一种或多种化合物中金属化合物的量与任何金属阳离子交换成的总和沸石超过提供完全金属阳离子交换的沸石所需的沸石。该碱性组合物可适用于碱催化的反应,例如烯烃的双键异构化,芳族化合物的烷基化以及由链烷烃的氧化生成伯烷醇和/或醛。

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