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Process for the preparation of poly(arylene sulphides) which can be branched

机译:可以分支的聚亚芳基硫醚的制备方法

摘要

1. A process for the production of optionally branched polyarylene sulfides of a) 50 to 100 mol-% aromatic dihalogen compounds corresponding to the following formula see diagramm : EP0215259,P7,F1 and 0 to 50 mol-% aromatic dihalogen compounds corresponding to the following formula see diagramm : EP0215259,P7,F2 in which the X's represents halogens, such as chlorine, or bromine, in the meta- or para-position to one another, the R**1 's may be the same or different and represent hydrogen, alkyl, cycloalkyl, aryl, alkylaryl, arylalkyl ; two substituents R**1 in the ortho position to one another may be attached to form an aromatic or heterocyclic ring and one substituent R**1 is always different from hydrogen and b) 0 to 5 mol-%, based on the sum of the aromatic dihalogen compounds corresponding to formulae I and II, of an aromatic tri- or tetrahalogen compound corresponding to the following formula ArXn in which Ar is an aromatic or heterocyclic radical, X is halogen and n is the number 3 or 4 and c) 50 to 99 mol-% sodium or potassium sulfide and 1 to 50 mol-% sodium or potassium hydrogen sulfide, the molar ratio of (a+b):c being from 0.75:1 to 1.15:1, in d) an organic solvent using catalysts and/or cosolvents, the molar ratio of sulfide and hydrogen sulfide c) to the organic solvent d) being in the range from 1:2 to 1:15, characterized in that the optionally continuous reaction is carried out by adding the solvent, the aromatic halogen compounds of formulae I, II and III and the hydrogen sulfides and sulfides with the catalysts and/or cosolvents in anhydrous form simultaneously or successively to the reaction mixture, solids used having a particle size in the range from 1 to 5000 micrometers.
机译:1.一种生产任选支化的聚芳撑硫醚的方法,其a)对应于下式的50至100mol%的芳族二卤化合物参见示意图:EP0215259,P7,F1和对应于下式的0至50mol%的芳族二卤化合物。下式参见图表:EP0215259,P7,F2其中X彼此之间互位或对位表示卤素,例如氯或溴,R ** 1可以相同或不同,并且代表氢,烷基,环烷基,芳基,烷基芳基,芳基烷基;彼此邻位的两个取代基R ** 1可以连接形成芳族或杂环,并且一个取代基R ** 1总是与氢不同,并且b)基于总和为0至5摩尔%。对应于下式ArXn的芳族三或四卤素化合物的相应于式I和II的芳族二卤素化合物,其中Ar为芳族或杂环基,X为卤素且n为3或4且c)50 -99摩尔%的硫化钠或硫化钾和1-50摩尔%的硫化氢钠或钾,(d)(a + b):c的摩尔比为0.75:1-1.15:1,催化剂和/或助溶剂,硫化物和硫化氢c)与有机溶剂d)的摩尔比为1:2至1:15,其特征在于,通过加入溶剂进行可选的连续反应,式I,II和III的芳香族卤素化合物以及具有与反应混合物同时或相继地以无水形式存在的催化剂和/或助溶剂,所使用的固体的粒径为1至5000微米。

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