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Method of extracting dinitrogen pentoxide from a mixture of dinitrogen pentoxide and nitric acid

机译:从五氧化二氮和硝酸的混合物中提取五氧化二氮的方法

摘要

Method of extracting dinitrogen pentoxide (N2O5) from its mixture in nitric acid, which consists of providing a solution of the mixture in an inert organic solvent, stripping out the N2O5 from solution in a carrier gas stream containing ozone, and subsequently condensing the N2O5 out of the gas stream by contact with further inert organic solvent. The presence of ozone suppresses the dissociation of the N2O5 transferred to the gas stream into dinitrogen tetroxide (N2O4). In a preferred embodiment the stripping and absorbing steps take place continuously in adjacent stripping and absorbing columns respectively having organic solvent recirculating through each.
机译:从硝酸中的混合物中提取五氧化二氮(N2O5)​​的方法,该方法包括在惰性有机溶剂中提供混合物的溶液,在含臭氧的载气流中从溶液中汽提N2O5,然后将N2O5冷凝出来通过与另外的惰性有机溶剂接触来除去气流。臭氧的存在抑制了转移到气流中的N2O5分解成四氧化二氮(N2O4)。在一个优选的实施方案中,汽提和吸收步骤在相邻的汽提和吸收塔中连续进行,相邻的汽提和吸收塔分别使有机溶剂循环通过。

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