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Supported catalyst containing rhenium and aluminum, a process for preparing the same, and a process for using the catalyst as a catalyst for metathesis reaction of olefins
Supported catalyst containing rhenium and aluminum, a process for preparing the same, and a process for using the catalyst as a catalyst for metathesis reaction of olefins
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机译:包含rh和铝的负载型催化剂,其制备方法以及使用该催化剂作为烯烃复分解反应的催化剂的方法
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摘要
The present invention relates to a novel catalyst supported on an organic or inorganic support based on a compound containing rhenium and aluminum represented by the following general formula:;O3Re-O-[Al (OR) (L)x-O]n-ReO3;Wherein R comprises a hydrocarbon residue such as alkyl, cycloalkyl, alkenyl, aryl, and chrysunallized aryl or cycloalkyl wherein R contains from 1 to 40 carbon atoms and the moiety is substituted with one or more alkoxy groups or And L is a synthetic solvent, x is 0 or 1, and n is an integer of 1 to 10. The present invention also relates to a process for preparing the catalyst and a process for using the catalyst in the metathesis reaction of olefins.
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机译:本发明涉及一种新型催化剂,该新型催化剂负载在基于以下通式表示的含rh和铝的化合物的有机或无机载体上:O 3 Sub> Re-O- [Al(OR)( L) x Sub> -O] n Sub> -ReO 3 Sub>;其中R包括烃基,例如烷基,环烷基,烯基,芳基和芳基或环烷基,其中R含有1至40个碳原子,并且该部分被一个或多个烷氧基取代,或者L是合成溶剂,x是0或1,并且n是1至10的整数。本发明还涉及制备催化剂的方法和在烯烃的复分解反应中使用该催化剂的方法。
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