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A method of manufacturing the same with the functional group density control polyamine

机译:一种具有官能团密度控制多胺的制造方法

摘要

It is a method of manufacturing a polyamine containing a carbon double bond - reactive carbon and tertiary amine groups or different pendant secondary amine controlled amount of (57) and the pendant tertiary amine groups in an amount that is [Abstract] Control Te, reactive carbon and pendant aldehyde groups of a controlled amount - to reductive amination with a second amine group of the first all aldehyde groups essentially polyaldehyde containing a carbon double bond, poly (tertiary amine and generating a), the steps of hydroformylation of (tertiary amine) Poly with pendant aldehyde groups of a controlled amount, the first the first or second amine (tertiary amine) Poly with pendant aldehyde groups method comprising the step of reductive amination with an amine 2. In another embodiment of the present invention for manufacturing a polyamine, the reductive amination of the aldehyde groups of a controlled amount by reductive amination of the polyaldehyde with a second amine first predetermined amount, the first or second amine addition The reductive amination of aldehyde groups all substantially the rest by reductive amination of secondary amines. In yet another aspect of the present invention for preparing a polyamine containing a secondary amine group and pendant third controlled amount of I to produce a polyamine having secondary amine groups and a pendant tertiary amine controlled amounts of the desired I will reductive amination poly aldehyde with a mixture of primary amines and secondary amines in the relative amounts required to.
机译:它是一种制造多胺的方法,该多胺包含碳双键-活性碳和叔胺基团或不同的侧链仲胺控制量(57)和侧链叔胺基团,其数量为[摘要]控制Te,活性碳和控制量的侧醛基-用第一全部醛基中的第二胺基进行还原胺化,基本上是含有碳双键的多醛,聚(叔胺并生成α),(叔胺)聚的加氢甲酰化步骤在具有可控制量的侧醛基的情况下,具有侧醛基的第一第一或第二胺(叔胺)方法包括用胺2进行还原性胺化的步骤。通过用第二胺第一前体对多醛进行还原胺化,控制数量的醛基的还原胺化预定量,第一或第二胺的加成醛基的还原胺化基本上全部是通过仲胺的还原胺化而其余的。在本发明的又一个方面,用于制备含有仲胺基和侧基第三控制量的I的多胺,以生产具有仲胺基和侧基叔胺控制量的所需的I的聚胺,将所需的I还原胺化多醛。所需相对量的伯胺和仲胺的混合物。

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