首页> 外国专利> GLASS COMPOSITE MATERIAL, PRECURSOR FOR THE MATERIAL, NITROGEN-CONTAINING COMPOSITE MATERIAL, LIGHT EMITTING ELEMENT, ELECTROPHOTOGRAPHIC PHOTORECEPTOR, NONLINEAR OPTICAL ELEMENT AND LASER ELEMENT

GLASS COMPOSITE MATERIAL, PRECURSOR FOR THE MATERIAL, NITROGEN-CONTAINING COMPOSITE MATERIAL, LIGHT EMITTING ELEMENT, ELECTROPHOTOGRAPHIC PHOTORECEPTOR, NONLINEAR OPTICAL ELEMENT AND LASER ELEMENT

机译:玻璃复合材料,材料前体,含氮复合材料,发光元件,光电照相感光体,非线性光学元件和激光元件

摘要

PURPOSE: To produce various optical elements such as a light emitting element excellent in durability by using a glass composite material chemical cross-linked to a glass matrix with the polymer chain such as polysilane consisting of a reticular structure of metal oxide. CONSTITUTION: This glass composite material is the one chemically cross-linked to a glass matrix having a polymer chain such as the copolymer of the polysilane, polygermane and polystannane and a reticular structure of a metal atom-oxygen atom-metal atom linkage, and the volume resistivity measured by the flat-disk electrode method while setting the voltage/film thickness at 106 V/cm is controlled to =3×106 Ω.cm. The composite material is derived by the CVD process, etc., from the polymer compds. as precursors shown by formulas I and II (M is SiGeSn, and R1 and R2 are each a 1-15C alkyl, aryl and aralkyl) and formulas III and IV (M is the same as before, R11 to R15 are the same as R1 or H except R14 ). Especially, the polysilanes of formulas III and IV are cross-linked to one another through oxygen atom, and the M-O linkage is advantageous to form a structure constituting the matrix.
机译:用途:通过使用通过聚合物链与玻璃基体化学交联的玻璃复合材料(例如由金属氧化物的网状结构组成的聚硅烷),生产各种光学元件(例如,耐久性优异的发光元件)。组成:这种玻璃复合材料是一种化学交联到具有聚合物链的玻璃基体上的材料,例如聚硅烷,聚锗烷和聚锡烷的共聚物以及金属原子-氧原子-金属原子键的网状结构,以及在将电压/膜厚设为10 6 V / cm的同时,将通过平板电极法测定的体积电阻率控制为≤3×10 6Ω·cm。该复合材料是通过CVD工艺等从聚合物混合物中得到的。如式I和II所示的前体(M为SiGeSn,并且R 1和R 2分别为1-15C烷基,芳基和芳烷基)和式III和IV(M与之前相同,R 11>至R 15与R 1或H相同,除了R 14)。特别地,式III和IV的聚硅烷通过氧原子彼此交联,并且M-O键有利于形成构成基质的结构。

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