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Balanced phosphoric acid plant cogeneration route

机译:平衡磷酸装置的热电联产路线

摘要

The present invention relates to the coproduction of a combustible gas stream usable as an energy source, a sulfur-dioxide-containing second gas stream usable as a source of oxidant in the gasification of coal, and a sulfur-dioxide-containing third gas stream usable as a feedstock for the production of sulfuric acid. The process includes heating coal in a coal gasification zone in the presence of an oxygen and sulfur dioxide-containing atmosphere under partial coal gasifying conditions to produce a carbonaceous char and a crude coal gas stream. Sulfur-containing compounds are removed from the coal gas stream and converted to elemental sulfur. The carbonaceous char is combined with gypsum to form a feed mixture. The non-gypsum portion of the feed mixture contains sufficient reducing potential to release substantially all of the sulfur in the gypsum as gaseous compounds of sulfur in a +4 or lower oxidation state. The feed mixture is heated under reducing conditions to produce a sulfur-dioxide-containing second gas stream recovered at an early stage of the reaction, a sulfur-dioxide-containing third gas stream and a solid sintered product. The sulfur-dioxide-containing second gas stream is recycled back to the gasification zone to provide the oxidant for the coal gasification.
机译:本发明涉及煤的气化的联产,所述的可燃气体可用作能源,在煤的气化中可用作氧化剂的含二氧化硫的第二气流,以及可用于煤炭气化的含二氧化硫的第三气流。作为生产硫酸的原料。该方法包括在部分煤气化条件下,在含氧和二氧化硫的气氛中,在煤气化区中加热煤,以生产碳质焦炭和粗煤气流。从煤气流中除去含硫化合物,并将其转化为元素硫。将碳质炭与石膏混合形成进料混合物。进料混合物的非石膏部分含有足够的还原能力,以释放出石膏中基本上所有的硫,作为+4或更低氧化态的硫的气态化合物。将进料混合物在还原条件下加热以产生在反应的早期回收的含二氧化硫的第二气流,含二氧化硫的第三气流和固体烧结产物。将含二氧化硫的第二气流再循环回到气化区,以提供用于煤气化的氧化剂。

著录项

  • 公开/公告号GR3022379T3

    专利类型

  • 公开/公告日1997-04-30

    原文格式PDF

  • 申请/专利权人 FLORIDA INSTITUTE OF PHOSPHATE RESEARCH;

    申请/专利号GR19960403508T

  • 发明设计人 MARTEN JEROME H.;

    申请日1997-01-28

  • 分类号C01B17/06;C10J3/00;

  • 国家 GR

  • 入库时间 2022-08-22 03:27:02

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