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Alkenyl succinic acid derivatives as metal working agents
Alkenyl succinic acid derivatives as metal working agents
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机译:烯基琥珀酸衍生物作为金属加工剂
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摘要
The present invention relates to salts of alkenylsuccinic acid alkoxyalkyl monoamides of the formula Ia and/or Ib IMAGE if desired mixed with salts of alkenylsuccinic acid monoester amines of the formula IIa and/or IIb IMAGE an/or alkenylsuccinimides of the formula III IMAGE where R1, R2, A, R3, R4, n, m and M(+) have the meaning mentioned in the description. The invention likewise relates to a process for the preparation of salts of alkenylsuccinic acid alkoxyalkyl monoamides of the formula Ia and/or Ib, if desired mixed with salts of alkenylsuccinic acid monoester amines of the formula IIa, IIb and/or alkenylsuccinimides of the formula III, which is characterised in that alkenylsuccinic anhydrides are reacted with alkoxyalkylamines of the formula IV H2N-(CH2)n-O-(A)m-R3 IV where R3, n, m and A have the meaning mentioned in the description, and this reaction is carried out in the presence of an amount of base equimolar to the alkoxyalkylamines of the formula IV or following the reaction an amount of base equimolar to the alkoxyalkylamines of the formula IV is added. The invention further relates to water- and/or oil-containing formulations for the working of metals, which contain the abovementioned salts of alkenylsuccinic acid alkoxyalkyl monoamides of the formula Ia and/or Ib, if desired mixed with salts of alkenylsuccinic acid monoester amines of the formula IIa and/or IIb and/or alkenylsuccinimides of the formula III, and to their use as anticorrosion agents, cooling lubricants and metalworking aids.
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机译:如果需要的话,本发明涉及式Ia和/或Ib的烯基琥珀酸烷氧基烷基单酰胺的盐与式IIa和/或IIb的烯基琥珀酸单酯胺的盐混合和/或式I的烯基琥珀酰亚胺III <图像>其中R 1,R 2,A,R 3,R 4,n,m和M(+)具有描述中提及的含义。本发明同样涉及制备式Ia和/或Ib的烯基琥珀酸烷氧基烷基单酰胺的盐,如果需要的话与式IIa,IIb的烯基琥珀酸单酯胺的盐和/或式III的烯基琥珀酰亚胺的盐的制备方法。 ,其特征在于烯基琥珀酸酐与式IV H 2 N-(CH 2)n O-(A)m R 3 IV的烷氧基烷基胺反应,其中R 3,n,m和A具有说明书中所述的含义,并且该反应在与式IV的烷氧基烷基胺等摩尔的碱存在下进行,或者在反应后加入与式IV的烷氧基烷基胺等摩尔的碱。本发明进一步涉及用于金属加工的含水和/或油的制剂,其含有上述式Ia和/或Ib的链烯基琥珀酸烷氧基烷基单酰胺的盐,如果需要的话,其与式Ia和/或Ib的链烯基琥珀酸单酯胺的盐混合。式IIIa和/或IIb和/或式III的烯基琥珀酰亚胺,以及它们作为防腐剂,冷却润滑剂和金属加工助剂的用途。
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