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Process for the estimation of the pollution of a solvent with polycyclic aromatic hydrocarbons,

机译:估算溶剂对多环芳烃的污染的方法,

摘要

Estimating the pollution of a solvent by polycyclic aromatic hydrocarbons (HAPs) comprises, firstly, establishing a reference standard by: (i) obtaining X-UV spectra, between 190-400 nm, from X mixtures, each containing N pre-determined polycyclic aromatics at different known concentrations in a solvent transparent to UV; (ii) determining, for each of the X spectra, n reference wave lengths each of which showing the presence of at least one of the N polycyclic aromatics in the mixture; (iii) measuring, for each spectrum, the absorbences corresponding to each of the n reference wavelengths; (iv) summation of the measured absorbences for each X spectrum and division of the sun obtained by the total concentration of the N compounds to give, for each spectrum, a value Z; and (v) calculation from each of the X-Z values of a reference constant K statistically representative of the X-Z values; and then, in subsequent stages, the determination of an index I of the total HAP concentrations in the UV-transparent solvent by: (a) obtaining a global UV spectrum at 190-400 nm of the solvent containing the HAPs; (b) measurement of the absorbences at the peaks appearing at or in proximity to the N reference wavelengths; (c) summation of the absorbences to obtain a value D; and (d) obtaining a concentration index I of total aromatics obtained in the solvent by application of the formula I = D/K in which I is the concentration in total HAPs, D is the sum of absorbences, and K is the reference constant.
机译:估计多环芳烃(HAP)对溶剂的污染包括,首先通过以下方法建立参考标准:(i)从X混合物中获得190-400 nm之间的X-UV光谱,每种混合物均包含N个预定的多环芳烃在对UV透明的溶剂中以不同的已知浓度; (ii)对于每个X光谱,确定n个参考波长,每个参考波长显示混合物中存在N种多环芳族化合物中的至少一种; (iii)为每个光谱测量与n个参考波长中的每个对应的吸光度; (iv)对每个X光谱的测得的吸光度求和,再除以N种化合物的总浓度得到的太阳分度,得到每个光谱的Z值; (v)从每个X-Z值计算统计上代表X-Z值的参考常数K;然后,在随后的步骤中,通过以下步骤确定紫外线透明溶剂中总HAP浓度的指数I:(a)在190-400 nm处获得含有HAP的溶剂的全局UV光谱; (b)测量在N个参考波长处或附近出现的峰值处的吸光度; (c)将吸光度求和以获得值D; (d)通过使用式I = D / K获得在溶剂中获得的总芳族化合物的浓度指数I,其中I是总HAP中的浓度,D是吸光度之和,K是参考常数。

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