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Thermoplastic mixture based on biopolymers for the production of biodegradable moldings with improved properties, production of the mixture and use

机译:基于生物聚合物的热塑性混合物,用于生产性能改善的可生物降解模制品,混合物的生产和用途

摘要

The invention relates to a biopolymer-based thermoplastic mixture for producing biodegradable shaped bodies with improved properties and to the production and use of said mixture. The inventive biopolymer-based, especially starch-based thermoplastic mixture is characterised in that it contains lignin, and is used for producing biodegradable shaped bodies with improved properties, preferably improved mechanical properties. The mixture is preferably obtained by providing and mixing together the following: A) 100 parts by weight of one or several physiologically suitable, biodegradable polymeric materials which can be processed thermoplastically from the group of polysaccharides and proteins; preferably of at least one starch of choice which is native, chemically modified, fermentative, recombinant and/or produced by biotransformation and/or of derivatives of said starches; B) 10 to 100 parts by weight of water; C) 1 to 100 parts by weight of lignin; D) optionally, up to 50 parts by weight of at least one plasticiser; and E) optionally, up to 200 parts by weight, preferably not more than 100 parts by weight of other usual additives. The constituents are thermoplasticised through the introduction of thermal and mechanical energy into the mixture, preferably at a high temperature with shearing forces being exerted on the mixture at the same time. The use of lignin with biopolymer-based, especially starch-based thermoplastic materials surprisingly produces improved thermoplastic materials which have advantages, especially in terms of their mechanical properties or other useful properties.
机译:本发明涉及用于生产具有改善的性能的可生物降解的成型体的基于生物聚合物的热塑性混合物,并且涉及所述混合物的生产和使用。本发明的基于生物聚合物的,特别是基于淀粉的热塑性混合物的特征在于,其包含木质素,并用于生产具有改善的性能,优选改善的机械性能的可生物降解的成型体。优选通过提供以下各项并将其混合在一起而获得混合物:A)100重量份的一种或几种生理上合适的,可生物降解的聚合物材料,其可以从多糖和蛋白质的组中热塑性地加工;优选至少一种选择的淀粉,其是天然的,化学改性的,发酵的,重组的和/或通过生物转化产生的和/或所述淀粉的衍生物; B)10至100重量份的水; C)1至100重量份的木质素; D)任选地,至多50重量份的至少一种增塑剂; E)任选地,至多200重量份,优选不大于100重量份的其他常用添加剂。通过向混合物中引入热能和机械能将组分热塑性化,优选在高温下,同时将剪切力施加在混合物上。木质素与基于生物聚合物的,特别是基于淀粉的热塑性材料的使用令人惊讶地产生了改进的热塑性材料,该热塑性材料具有优点,特别是在其机械性能或其他有用性能方面。

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