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Method for making Zr alloy nuclear reactor fuel cladding having excellent corrosion resistance and creep properties

机译:具有优异的耐腐蚀性和蠕变性能的锆合金核反应堆燃料包壳的制备方法

摘要

The invention provides a method for making Zr alloy nuclear reactor fuel cladding having excellent corrosion resistance and creep properties. The method includes performing hot forging, solution heat treatment, hot extruding, and repeated cycles of annealing and cold rolling of a Zr alloy including, by weight, 0.2 to 1.7% Sn, 0.18 to 0.6% Fe, 0.07 to 0.4% Cr and 0.05 to 1.0% Nb, with the remainder being Zr and incidental impurities, and the incidental nitrogen impurity content being 60 ppm or less, and then performing final stress relief annealing thereon. The annealing is performed at a temperature of 550 C. to 850 C. for 1 to 4 hours such that the accumulated annealing parameter Ai=tiexp(-40,000/Ti) satisfies relationships -20 log Ai-15, and -18-10X. sub.Nb log Ai-15-3.75 (X.sub.Nb -0.2), wherein Ai represents the annealing parameter for the i- th annealing, ti represents the annealing time (hours) for the i-th annealing, Ti represents the annealing temperature (K) for the i-th annealing, and X. sub.Nb represents the Nb concentration (wt %).
机译:本发明提供了一种制备具有优异的耐腐蚀性和蠕变性能的Zr合金核反应堆燃料包壳的方法。该方法包括进行Zr合金的热锻,固溶热处理,热挤压以及退火和冷轧的重复循环,该Zr合金包括按重量计0.2%至1.7%的Sn,0.18%至0.6%的Fe,0.07%至0.4%的Cr和0.05%的Zr合金。 Nb为1.0%Nb,其余为Zr和附带杂质,附带氮杂质含量为60ppm以下,然后进行最终的应力消除退火。退火在550℃至850℃的温度下进行1至4小时,使得累积的退火参数Ai = tiexp(-40,000 / Ti)满足-20logAi-15和-18-10X的关系。 sub.Nb log Ai-15-3.75(X.Nb -0.2),其中Ai代表第i次退火的退火参数,ti代表第i次退火的退火时间(小时),Ti代表第i次退火的退火温度(K),X Nb表示Nb浓度(wt%)。

著录项

  • 公开/公告号US6125161A

    专利类型

  • 公开/公告日2000-09-26

    原文格式PDF

  • 申请/专利权人 MITSUBISHI MATERIALS CORPORATION;

    申请/专利号US19990397094

  • 发明设计人 TAKESHI ISOBE;YOSHITAKA SUDA;

    申请日1999-09-16

  • 分类号G21C3/07;C22C16/00;C22F1/18;

  • 国家 US

  • 入库时间 2022-08-22 01:36:05

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