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24--135- Optically active substituted 24-diamino-135-triazines as herbicides

机译:24--135-光学活性取代的24-二氨基-135-三嗪类除草剂

摘要

The present invention relates to a method and a novel intermediate for herbicides and these optically active a 2,4-diamino-1,3,5-triazine, of producing the novel substituted of formula (I) relates to him for:; [Formula I]; Wherein; Ar represents an optionally substituted aryl, wherein aryl is phenyl, naphthyl, pyridinyl, pyrimidinyl, furyl, benzofuryl, thienyl and benzothienyl from the group consisting of carbonyl carbocyclic or heterocyclic, monocyclic or can represent a bicyclic, aromatic group substituents are cyano, nitro, carbamoyl, thio carbamoyl, halogen, C 1 -C 4 - alkyl, C 1 -C 4 - halogenoalkyl, C 1 -C 4 - alkoxy, C 1 -C 4 - halogenoalkyl alkoxy, C 1 -C 4 - alkylthio, C 1 -C 4 - halogenoalkyl alkylthio, C 1 -C 4 - alkylsulfinyl, C 1 -C 4 - halogenoalkyl alkyl sulfinyl, C 1 -C 4 - alkylsulfonyl, C 1 -C 4 - halogenoalkyl alkylsulfonyl, C 1 -C 4 - alkylamino and C 1 -C 4 - is selected from the group consisting of alkoxycarbonyl ,; R 1 denotes an alkyl having 1 to 4 carbon atoms,; R 2 is optionally having 1 to 4 carbon atoms hydroxyl-, cyano-, halogen- or C 1 -C 4 - alkoxy - represents an optionally substituted alkyl,; R 3 is optionally having from 2 to 4 carbon atoms cyano-, halogen- or C 1 -C 4 - alkoxy - represents a substituted alkyl,; Where R 1 is bonded to the substituent on the carbon atom which is arranged in R form.
机译:本发明涉及一种除草剂的方法和新的中间体,这些中间体具有2,4-二氨基-1,3,5-三嗪的旋光活性,其制备式(Ⅰ)的新型取代基涉及: [式I];其中Ar表示任选取代的芳基,其中芳基是苯基,萘基,吡啶基,嘧啶基,呋喃基,苯并呋喃基,噻吩基和苯并噻吩基,其选自羰基碳环或杂环,单环或可以表示双环的芳基,取代基是氰基,硝基,氨基甲酰基,硫代氨基甲酰基,卤素,C 1 -C 4 -烷基,C 1 -C 4 -卤代烷基,C 1 -C 4 -烷氧基,C 1 -C 4 -卤代烷基烷氧基,C 1 -C 4 -烷硫基,C 1 -C 4 -卤代烷基烷硫基,C 1 -C 4 -烷基亚磺酰基,C 1 -C 4 -卤代烷基烷基亚磺酰基,C 1 -C 4 -烷基磺酰基,C 1 -C 4 -卤代烷基烷基磺酰基,C 1 -C 4 -烷基氨基和C 1 -C 4 -选自烷氧羰基, R 1 表示具有1-4个碳原子的烷基; R 2 任选具有1-4个碳原子,羟基,氰基,卤素或C 1 -C 4 -烷氧基-表示任选取代的烷基; R 3 可选具有2至4个碳原子氰基,卤素或C 1 -C 4 -烷氧基-表示取代的烷基,;其中R 1 与以R形式排列的碳原子上的取代基键合。

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