首页> 外国专利> Supported catalyst for olefin polymerization comprises copolymer support, metallocene complex and metallocenium ion forming compound

Supported catalyst for olefin polymerization comprises copolymer support, metallocene complex and metallocenium ion forming compound

机译:用于烯烃聚合的负载催化剂包括共聚物载体,茂金属配合物和茂金属离子形成化合物

摘要

A supported catalyst for olefin polymerization comprises a copolymer support, a metallocene complex and a metallocenium ion forming compound. A supported catalyst (I) for olefin polymerization comprises: (A) a support comprising a copolymer containing (A1) monomer units of formula R1C(R2)H=CH2 (I), (A2) monomer units of formula (II) and (A3) monomer units having polar groups; (B) a metallocene complex and (C) a metallocenium ion forming compound. R1 = H, 1-4C alkyl or phenyl; R2 = aryl, optionally substituted, alkyl or alkenyl; A1 = a chemical bond or a phenylene group, optionally substituted; R3-R7 = H, 1-10C alkyl or phenyl, optionally substituted; and p = 0-8. Independent claims are included for: (i) a process for the production of the catalyst (I) by solution polymerization of the monomer units (A1), (A2) and (A3) to form a copolymer solution followed by addition of (B) and (C); (ii) a process for the polymerization of olefins in the presence of the catalyst (I); and (iii) the copolymer support (A).
机译:用于烯烃聚合的负载催化剂包括共聚物载体,茂金属配合物和茂金属离子形成化合物。用于烯烃聚合的负载型催化剂(I)包括:(A)包含共聚物的载体,所述共聚物包含(A1)式R 1 C(R 2)H = CH 2的单体单元(I),(A2)单体单元具有极性基团的式(II)和(A3)单体单元; (B)茂金属配合物和(C)茂金属离子形成化合物。 R 1 = H,1-4C烷基或苯基; R 2 =芳基,任选取代的烷基或烯基; A 1 =任选取代的化学键或亚苯基; R 3 -R 7 = H,1-10C的烷基或苯基,任选被取代;并且p = 0-8。包括以下独立权利要求:(i)通过单体单元(A1),(A2)和(A3)的溶液聚合形成共聚物溶液,然后添加(B)来制备催化剂(I)的方法。和(C); (ii)在催化剂(I)的存在下烯烃聚合的方法; (iii)共聚物载体(A)。

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