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Optimum integration of Fischer-Tropsch synthesis and syngas production

机译:费-托合成和合成气生产的最佳集成

摘要

A method is described for conversion of natural gas or other fossil fuels to higher hydrocarbons, comprising the following steps: a) reaction of natural gas with steam and oxygenic gas in at least one reforming zone in order to produce a synthesis gas consisting primarily of hydrogen and CO, in addition to some carbon dioxide; b) passing said synthesis gas to a Fisher-Tropsch reactor in order to produce a crude synthesis stream consisting of lower hydrocarbons, water and non-converted synthesis gas; c) separation of said crude synthesis stream in a recovery zone, into a crude product stream mainly containing heavier hydrocarbons, a water stream and a tail gas stream mainly containing the remaining constituents; which is charaterized in that the method also comprises the following steps; d) stream reformation of at least part of the tail gas in a separate steam reformer; e) introduction of the reformed tail gas into the gas stream before this is led into the Fischer-Tropsch reactor.
机译:描述了一种用于将天然气或其他化石燃料转化成高级烃的方法,其包括以下步骤:a)天然气在至少一个重整区中与蒸汽和氧气反应,以产生主要由氢组成的合成气除了一些二氧化碳,还有一氧化碳; b)将所述合成气通入Fisher-Tropsch反应器中,以产生由低级烃,水和未转化的合成气组成的粗合成流; c)在回收区中将所述粗合成物流分离成主要含有重烃的粗产物物流,主要含有其余成分的水物流和尾气物流;其特征在于该方法还包括以下步骤; d)在单独的蒸汽重整器中将至少部分尾气进行物流重整; e)在将重整尾气引入费-托反应器之前,先将其引入气流中。

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