An elastomeric article (e.g., glove, condom, etc.) that includes a chemical protection layer that will not substantially dissolve when applied with certain chemicals or solvents, such as methyl methyacrylate, is provided. The chemical protection layer contains at least one crosslinked, modified silicone elastomer. For example, in one embodiment, the modified silicone chemical protection layer covers the outer surface of a styrene-ethylene-butylene-styrene (S-EB-S) block copolymer substrate body to impart relative chemical resistance to the resulting elastomeric article.
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