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COBALT (III) ENCAPSULATED NICKEL HYDROXIDES AND BASIC CARBONATES FOR BATTERY ELECTRODES

机译:钴(III)包封的镍氢氧化物和电池用碱性碳酸盐

摘要

A process for producing a cobalt III encapsulated nickel hydroxide or basic nickel carbonate product including the steps of: (i) providing an ammoniacal solution including cobalt ammine complexes and nickel II ammine complexes; (ii) progressively lowering the ammonia content to sequentially precipate the nickel as an hydroxide or basic carbonate; and (iii) further lowering the ammonia content to precipitate the majority of the cobalt as cobalt III oxide hydroxide; wherein the majority of cobalt III oxide hydroxide coats on the surface of the precipitate nickel hydroxide or basic nickel carbonate to form a coated particle.
机译:一种包封有钴Ⅲ的氢氧化镍或碱性碳酸镍产物的方法,包括以下步骤:(i)提供一种氨溶液,其中包括钴胺配合物和镍Ⅱ胺配合物。 (ii)逐步降低氨含量,以使镍依次沉淀为氢氧化物或碱性碳酸盐; (iii)进一步降低氨含量,以沉淀出大部分的钴,成为III型氧化钴氢氧化物;其中大部分的氢氧化三钴氧化物涂覆在沉淀物氢氧化镍或碱性碳酸镍的表面上以形成涂覆的颗粒。

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