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2.2 - (diaryl) vinylphosphinverbindung, palladium catalyst, and process for the production of arylaminen, diarylen or arylalkynen with the catalyst
2.2 - (diaryl) vinylphosphinverbindung, palladium catalyst, and process for the production of arylaminen, diarylen or arylalkynen with the catalyst
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机译:2.2-(二芳基)乙烯基膦酸酯,钯催化剂以及用该催化剂生产芳基胺,二芳基或芳基炔的方法
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摘要
A novel 2,2-(diaryl)vinylphosphine compound represented by the following general formula (1): CHEM (wherein R1 is a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an alicyclic group having 5 to 7 carbon atoms, etc.; R2, R3, R4, R5, R6, and R7 may be the same or different and each is an alkyl group having 1 to 6 carbon atoms, an alicyclic group having 5 to 7 carbon atoms, etc., provided that R4 and R5 taken together and/or R6 and R7 taken together may represent a fused benzene ring, a substituted fused benzene ring, a trimethylene group, etc.; and p, q, r, and s each is 0 to 5, provided that p+q and r+s each is in the range of from 0 to 5); a palladium-phosphine catalyst obtained by causing a palladium compound to act on the novel 2,2-(diaryl)vinylphosphine compound; and a process for obtaining an arylamine, a diaryl and an arylalkyne in the presence of the palladium-phosphine catalyst.
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