Photoactive represented by the chemical formula (1) of the following (R) present invention, method of manufacturing the same - and phenoxy propionic acid -N- methyl -N-2- fluorophenyl amide compound, use of controlling the barnyard that occur in rice , the present invention relates to herbicidal mixture comprising these compounds. [Formula 1] Wherein: alkyl amino group of C 1 ~C 6 alkyl groups a hydrogen atom, a halogen atom, a hydroxy group, NH 2, CO 2 H, a C 1 ~C 3 is substituted one or two, X is, C alkyl group of 1 ~C 6, alkoxy group of C 1 ~C 6, haloalkyl group of C 1 ~C 3, haloalkoxy group C 1 ~C 3, alkoxyalkoxy group C 2 ~C 4, C 1 ~C thionyl alkyl group having 1-4 alkylsulfonyl group C 1 ~C 4, alkenyl C 2 ~C 6, an alkynyl group of C 2 ~C 6, alkenyl group of C 2 ~C 6, the C 2 ~C 6 The Y, indicates hydrogen or fluoro atom, and (F);; represents an alkyl group of C 1 ~C 3 or alkoxycarbonyl group, alkynyl group, a C 1 ~C 3 n is 0, 1 or 2 An integer n is 2, X can be a combination of different substituted compounds respectively.
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