首页> 外国专利> PROCEDURE FOR OBTAINING A WATERPROOF DISPERSION OF PARTICLES FORMED BY A POLYMER AND A FINALLY DIVIDED ORGANIC SOLID PRODUCT.

PROCEDURE FOR OBTAINING A WATERPROOF DISPERSION OF PARTICLES FORMED BY A POLYMER AND A FINALLY DIVIDED ORGANIC SOLID PRODUCT.

机译:获得由聚合物和最终划分为有机固体产品制成的颗粒的防水分散性的程序。

摘要

Process for obtaining an aqueous dispersion, formed by a polymer and making available particles composed of finely divided inorganic solid substance, in which at least one ethylenically unsaturated monomer is distributed in the aqueous medium in a dispersed form and polymerized by at least one polymerization initiator by means of radicals in the presence of at least one inorganic solid substance, finely divided and distributed in a dispersed form and at least one dispersant according to the method of aqueous emulsion polymerization by means of radicals, characterized in that a) an aqueous and stable dispersion of at least one inorganic solid substance is used, which is characterized in that it contains in an initial solid product concentration of 1% by weight, based on the aqueous dispersion of at least one solid substance, still one hour after obtaining more than 90% by weight of the substance s Dispersed liquid in its origin in dispersed form and its dispersed solid substance particles show an average diameter by weight at 100 nm, b) the dispersed solid substance particles of at least one inorganic solid substance shown in an aqueous normalized potassium chloride solution at a pH value, the pH value of the aqueous reaction medium at the start of emulsion polymerization, an electrophoretic mobility other than zero, and c) the radical generating component of at least one polymerization initiator by means of radicals and / or the dispersing effect component of at least one dispersant shows at least one electric charge, whose polarity is opposite to the polarity of the electrophoretic mobility of the dispersed solid substance particles of at least one solid substance, which show these in a solution of normalized and aqueous potassium chloride a pH value, which corresponds to the pH value of the aqueous reaction medium so at the beginning of emulsion polymerization.
机译:获得由聚合物形成的水分散体的方法,并提供由细碎的无机固体物质组成的颗粒,其中至少一种烯键式不饱和单体以分散的形式分布在水介质中,并通过至少一种聚合引发剂进行聚合。自由基是指在至少一种无机固体物质的存在下按照自由基通过水乳液聚合的方法以分散形式和至少一种分散剂细分并分布的特征,其特征在于a)水性稳定分散体使用至少一种无机固体物质的特征在于,其特征在于,基于至少一种固体物质的水分散体,其初始固体产物浓度大于1重量%,在获得超过90%的无机盐后仍保持一小时。 s占物质重量的百分比s起源于分散液的分散液形式,其分散的固体物质颗粒图1s显示出按重量计的平均直径<100 nm,b)在pH值的标准化氯化钾水溶液中显示的至少一种无机固体物质的分散固体物质颗粒,起始时是水性反应介质的pH值乳液聚合,电泳迁移率不为零以及c)至少一种聚合引发剂通过自由基产生的组分和/或至少一种分散剂的分散作用组分显示至少一种电荷,其极性为与至少一种固体物质的分散固体物质颗粒的电泳迁移率的极性相反,后者在归一化和氯化钾水溶液中显示的pH值对应于水性反应介质的pH值乳液聚合的开始。

著录项

  • 公开/公告号ES2231260T3

    专利类型

  • 公开/公告日2005-05-16

    原文格式PDF

  • 申请/专利权人 BASF AKTIENGESELLSCHAFT;

    申请/专利号ES20000962418T

  • 发明设计人 XUE ZHIJIAN;WIESE HARM;

    申请日2000-08-31

  • 分类号C08F292/00;C08F2/44;

  • 国家 ES

  • 入库时间 2022-08-21 22:14:47

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